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Sodium cyanate - NACNO

85%, remainder sodium carbonate #054685

Chemical Product and Company Identification

   MSDS Name Sodium cyanate, 88 - 92 %
remainder sodium carbonate,carbamide
   Synonyms Cyansan, Cyanic acid, sodium salt, Natriumcyanat 9 (German),Cianato de sodio (Spanish),Cyanate de sodium (French)
   Company Sai Chem Group of Companies
Ahmedbad, Gujarat, India

Composition on Ingredients

CAS#

Chemical Name

Percent

EINECS/ELINCS

917-61-3

Sodium cyanate

88 - 92

213-030-6

497-19-8

Sodium carbonate

>5

207-838-8

 
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Physical and Chemical Properties

Property

Description

Name Sodium Cyanate
(Cyanic Acid Sodium Salt)
Chemical Formula NaOCN
Molecular Weight 65.015
Physical State Free flowing powder
Appearance White
Odour Odourless
Freezing/Melting Point 550ºC
Density 2.108 g/cm3
Solubility 5 gm at 25ºC
Purity 88% to 92%
Soda Ash Content > 5%
Cyanate (-OCN) Content 59.5 % to 61.3 %
NaCN Content Almost Nil
Loss on Drying (At 110ºC)Max > 0.05 %
pH of Solution in Water (5 Wt %) 10 to 11
 
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Hazards Identification

Appearance: off-white crystalline powder.
Target Organs: Respiratory system, eyes, skin.
Warning: Causes eye, skin, and respiratory tract irritation. May be harmful if swallowed.

Potential Health Effects
Eye: Causes eye irritation.
Skin: Causes skin irritation.
Ingestion: May cause irritation of the digestive tract. Human fatalities have been reported from acute poisoning.
Inhalation: Causes respiratory tract irritation.
Chronic: No information found.

First Aid Measures

Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion: Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation.
Notes to Physician: Treat symptomatically and supportively

Fire Fighting Measures

General Information: As in any fire, wear a self-contained breathing apparatus in pressure-deman, and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media: Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.
Flash Point: Not available.
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: (estimated) Health: 2; Flammability: 1; Instability: 0

Accidental Release Measures

General Information: Use proper personal protective equipment.
Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Provide ventilation.

 
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Applications

Cyanic acid (also called fulminic acid) is an unstable - explosive, poisonous, volatile, clear liquid with the structure of H-O-C?N - the oxoacid formed from the pseudohalogen cyanide, which readily polymerizes to cyamelide and fulminic acid. Cyanuric acid (also called pyrolithic acid), white monoclinic crystal with the structure of [HOC(NCOH)2N], is the compound of polymerized cyanic acid.

Cyanic acid hydrolyses to ammonia and carbon dioxide in water. Its salts and esters are cyanates. Esters of normal cyanic acid are not known. There is another isomeric cyanic acid with the structure of H-N=C=O, which is called isocyanic acid. Its salts and esters are isocyanates.

Cyanates are used in the manufacturing pharmaceuticals, pesticides, textile softener, lubricants and industrial disinfectants through the conversion to polycyclic compounds.

Used as plastic additives and as heat treatment salt formulations for metals. In chemcial reaction, sodium cyanate is used for the synthesis urea derivatives mainly and other pesticide and dyes intermediates. It is used directly as a herbicide.


• Meta Uriedo Aniline & isoproturon & other herbicides products

• Urea derivatives are obtained by reaction with amines.

• Herbicides, Mainly to destroy weeds in lawns and onion crops, Simultaneously it act as fertilizer.

• It is also used in the syntheses of pesticides, detergents and plastic additives.

 
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Handelling and Storage

Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid breathing dust.
Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

 
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Exposure Controls, Personal Protection

Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.

Exposure Limits

Chemical Name

ACGIH

NIOSH

OSHA - Final PELs

Sodium cyanate

none listed

none listed

none listed

Sodium carbonate

none listed

none listed

none listed


OSHA Vacated PELs: Sodium cyanate: No OSHA Vacated PELs are listed for this chemical. Sodium carbonate: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Stability and Reactivity

Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: Dust generation, excess heat.
Incompatibilities with Other Materials: Strong acids.
Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.

Disposal Considerations


Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.

 
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Packaging

HDPE Bags inside liner of 20 Kgs, 25kgs, 40 Kgs & 50 Kgs. Capacity

 
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Additional Information

MSDS Creation Date: 1/05/1999
Revision #4 Date: 3/16/2007

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